{"_buckets": {"deposit": "b7256785-90ce-4933-83f2-f9f2f3bcc731"}, "_deposit": {"created_by": 18, "id": "8761", "owners": [18], "pid": {"revision_id": 0, "type": "depid", "value": "8761"}, "status": "published"}, "_oai": {"id": "oai:fukuyama-u.repo.nii.ac.jp:00008761", "sets": ["783"]}, "author_link": ["45807", "45810", "45806", "45805", "45305", "45809", "45808", "45081", "45075"], "item_10002_biblio_info_7": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2013-12-25", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "31", "bibliographicPageEnd": "23", "bibliographicPageStart": "23", "bibliographic_titles": [{"bibliographic_title": "福山大学薬学部研究年報"}, {"bibliographic_title": "Annual report of the Faculty of Pharmacy \u0026 Pharmaceutical Sciences, Fukuyama University", "bibliographic_titleLang": "en"}]}]}, "item_10002_description_5": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "Total syntheses of (±)-carquinostatin A (1), and (R)-(−)-carquinostatin A (1a) together with its enantiomer, (S)-(+)-carquinostatin A (1b), possessing radical scavenging activity, were newly achieved. (±)-Carquinostatin A (1) was synthesized from 1-acetonyl-6-bromo-3-ethoxy-2-methylcarbazole (6), which was derived from the known 1-acetonyl-3-ethoxy-2-methylcarbazole (5). Introduction of a prenyl group at the 6-position of carbazole was successful in two steps. For the synthesis of (R)-(−)-carquinostatin A (1a) and (S)-(+)-carquinostatin A (1b), (R)-(−)-1-(2-acetoxypropyl)-3-hydroxy-2-methylcarbazole (15a) and (S)-(+)-3-hydroxy-1-(2-hydroxypropyl)-2-methylcarbazole (15b), prepared by lipase-QLM catalyzed enantioselective transesterification of 3-hydroxy-1-(2-hydroxypropyl)-2-methylcarbazole (14), were used as the chiral starting material.", "subitem_description_type": "Abstract"}]}, "item_10002_description_6": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "Total syntheses of (±)-carquinostatin A (1), and (R)-(−)-carquinostatin A (1a) together with its enantiomer, (S)-(+)-carquinostatin A (1b), possessing radical scavenging activity, were newly achieved. (±)-Carquinostatin A (1) was synthesized from 1-acetonyl-6-bromo-3-ethoxy-2-methylcarbazole (6), which was derived from the known 1-acetonyl-3-ethoxy-2-methylcarbazole (5). Introduction of a prenyl group at the 6-position of carbazole was successful in two steps. For the synthesis of (R)-(−)-carquinostatin A (1a) and (S)-(+)-carquinostatin A (1b), (R)-(−)-1-(2-acetoxypropyl)-3-hydroxy-2-methylcarbazole (15a) and (S)-(+)-3-hydroxy-1-(2-hydroxypropyl)-2-methylcarbazole (15b), prepared by lipase-QLM catalyzed enantioselective transesterification of 3-hydroxy-1-(2-hydroxypropyl)-2-methylcarbazole (14), were used as the chiral starting material.", "subitem_description_type": "Other"}]}, "item_10002_full_name_3": {"attribute_name": "著者別名", "attribute_value_mlt": [{"nameIdentifiers": [{"nameIdentifier": "45808", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "9000367427671", "nameIdentifierScheme": "CiNii ID", "nameIdentifierURI": "http://ci.nii.ac.jp/nrid/9000367427671"}], "names": [{"name": "稗田, 雄三"}]}, {"nameIdentifiers": [{"nameIdentifier": "45075", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "9000005189344", "nameIdentifierScheme": "CiNii ID", "nameIdentifierURI": "http://ci.nii.ac.jp/nrid/9000005189344"}], "names": [{"name": "町支, 臣成"}]}, {"nameIdentifiers": [{"nameIdentifier": "45809", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "9000337100339", "nameIdentifierScheme": "CiNii ID", "nameIdentifierURI": "http://ci.nii.ac.jp/nrid/9000337100339"}], "names": [{"name": "内田, 佳成"}]}, {"nameIdentifiers": [{"nameIdentifier": "45305", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "9000005179805", "nameIdentifierScheme": "CiNii ID", "nameIdentifierURI": "http://ci.nii.ac.jp/nrid/9000005179805"}], "names": [{"name": "藤岡, 晴人"}]}, {"nameIdentifiers": [{"nameIdentifier": "45810", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "藤井, さゆり"}]}, {"nameIdentifiers": [{"nameIdentifier": "45081", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "9000014453717 ", "nameIdentifierScheme": "CiNii ID", "nameIdentifierURI": "http://ci.nii.ac.jp/nrid/9000014453717 "}], "names": [{"name": "日比野, 俐"}]}]}, "item_10002_publisher_8": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "福山大学薬学部"}]}, "item_10002_source_id_11": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AN10064550", "subitem_source_identifier_type": "NCID"}]}, "item_10002_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0288-724X", "subitem_source_identifier_type": "ISSN"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Hieda, Yuhzo"}], "nameIdentifiers": [{"nameIdentifier": "45805", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Choshi, Tominari"}], "nameIdentifiers": [{"nameIdentifier": "45806", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Uchida, Yoshinari"}], "nameIdentifiers": [{"nameIdentifier": "45807", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2017-12-20"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "31-23.pdf", "filesize": [{"value": "150.0 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensefree": "Copyright (c) 2013 by Fukuyama University", "licensetype": "license_free", "mimetype": "application/pdf", "size": 150000.0, "url": {"label": "稗田雄三(発表論文抄録(2012))", "url": "https://fukuyama-u.repo.nii.ac.jp/record/8761/files/31-23.pdf"}, "version_id": "7a420e94-0a84-4193-b68f-1566569bcc95"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "total synthesis", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "(±)-carquinostatin A", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "(R)-(−)-carquinostatin A", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "(S)-(+)-carquinostatin A", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "lipase-QLM", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "asymmetric synthesis", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "jpn"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "departmental bulletin paper", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "(±)-Carquinostatin Aの全合成と(R)-(−)-及び (S)-(+)-Carquinostatin Aの不斉全合成研究(発表論文抄録(2012))", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "(±)-Carquinostatin Aの全合成と(R)-(−)-及び (S)-(+)-Carquinostatin Aの不斉全合成研究(発表論文抄録(2012))"}, {"subitem_title": "Total Synthesis of (±)-Carquinostatin A, and Asymmetric Total Synthesis of (R)-(−)-Carquinostatin A and (S)-(+)-Carquinostatin A", "subitem_title_language": "en"}]}, "item_type_id": "10002", "owner": "18", "path": ["783"], "permalink_uri": "https://fukuyama-u.repo.nii.ac.jp/records/8761", "pubdate": {"attribute_name": "公開日", "attribute_value": "2017-12-20"}, "publish_date": "2017-12-20", "publish_status": "0", "recid": "8761", "relation": {}, "relation_version_is_last": true, "title": ["(±)-Carquinostatin Aの全合成と(R)-(−)-及び (S)-(+)-Carquinostatin Aの不斉全合成研究(発表論文抄録(2012))"], "weko_shared_id": -1}