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(±)-Carquinostatin Aの全合成と(R)-(−)-及び (S)-(+)-Carquinostatin Aの不斉全合成研究(発表論文抄録(2012))
https://fukuyama-u.repo.nii.ac.jp/records/8761
https://fukuyama-u.repo.nii.ac.jp/records/87612de2b834-3d3b-4325-a1e1-ca043abb2061
名前 / ファイル | ライセンス | アクション |
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Copyright (c) 2013 by Fukuyama University
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2017-12-20 | |||||
タイトル | ||||||
タイトル | (±)-Carquinostatin Aの全合成と(R)-(−)-及び (S)-(+)-Carquinostatin Aの不斉全合成研究(発表論文抄録(2012)) | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Total Synthesis of (±)-Carquinostatin A, and Asymmetric Total Synthesis of (R)-(−)-Carquinostatin A and (S)-(+)-Carquinostatin A | |||||
言語 | ||||||
言語 | jpn | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | total synthesis | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | (±)-carquinostatin A | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | (R)-(−)-carquinostatin A | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | (S)-(+)-carquinostatin A | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | lipase-QLM | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | asymmetric synthesis | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
著者 |
Hieda, Yuhzo
× Hieda, Yuhzo× Choshi, Tominari× Uchida, Yoshinari |
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著者別名 | ||||||
識別子Scheme | WEKO | |||||
識別子 | 45808 | |||||
識別子Scheme | CiNii ID | |||||
識別子URI | http://ci.nii.ac.jp/nrid/9000367427671 | |||||
識別子 | 9000367427671 | |||||
姓名 | 稗田, 雄三 | |||||
著者別名 | ||||||
識別子Scheme | WEKO | |||||
識別子 | 45075 | |||||
識別子Scheme | CiNii ID | |||||
識別子URI | http://ci.nii.ac.jp/nrid/9000005189344 | |||||
識別子 | 9000005189344 | |||||
姓名 | 町支, 臣成 | |||||
著者別名 | ||||||
識別子Scheme | WEKO | |||||
識別子 | 45809 | |||||
識別子Scheme | CiNii ID | |||||
識別子URI | http://ci.nii.ac.jp/nrid/9000337100339 | |||||
識別子 | 9000337100339 | |||||
姓名 | 内田, 佳成 | |||||
著者別名 | ||||||
識別子Scheme | WEKO | |||||
識別子 | 45305 | |||||
識別子Scheme | CiNii ID | |||||
識別子URI | http://ci.nii.ac.jp/nrid/9000005179805 | |||||
識別子 | 9000005179805 | |||||
姓名 | 藤岡, 晴人 | |||||
著者別名 | ||||||
識別子Scheme | WEKO | |||||
識別子 | 45810 | |||||
姓名 | 藤井, さゆり | |||||
著者別名 | ||||||
識別子Scheme | WEKO | |||||
識別子 | 45081 | |||||
識別子Scheme | CiNii ID | |||||
識別子URI | http://ci.nii.ac.jp/nrid/9000014453717 | |||||
識別子 | 9000014453717 | |||||
姓名 | 日比野, 俐 | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Total syntheses of (±)-carquinostatin A (1), and (R)-(−)-carquinostatin A (1a) together with its enantiomer, (S)-(+)-carquinostatin A (1b), possessing radical scavenging activity, were newly achieved. (±)-Carquinostatin A (1) was synthesized from 1-acetonyl-6-bromo-3-ethoxy-2-methylcarbazole (6), which was derived from the known 1-acetonyl-3-ethoxy-2-methylcarbazole (5). Introduction of a prenyl group at the 6-position of carbazole was successful in two steps. For the synthesis of (R)-(−)-carquinostatin A (1a) and (S)-(+)-carquinostatin A (1b), (R)-(−)-1-(2-acetoxypropyl)-3-hydroxy-2-methylcarbazole (15a) and (S)-(+)-3-hydroxy-1-(2-hydroxypropyl)-2-methylcarbazole (15b), prepared by lipase-QLM catalyzed enantioselective transesterification of 3-hydroxy-1-(2-hydroxypropyl)-2-methylcarbazole (14), were used as the chiral starting material. | |||||
内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Total syntheses of (±)-carquinostatin A (1), and (R)-(−)-carquinostatin A (1a) together with its enantiomer, (S)-(+)-carquinostatin A (1b), possessing radical scavenging activity, were newly achieved. (±)-Carquinostatin A (1) was synthesized from 1-acetonyl-6-bromo-3-ethoxy-2-methylcarbazole (6), which was derived from the known 1-acetonyl-3-ethoxy-2-methylcarbazole (5). Introduction of a prenyl group at the 6-position of carbazole was successful in two steps. For the synthesis of (R)-(−)-carquinostatin A (1a) and (S)-(+)-carquinostatin A (1b), (R)-(−)-1-(2-acetoxypropyl)-3-hydroxy-2-methylcarbazole (15a) and (S)-(+)-3-hydroxy-1-(2-hydroxypropyl)-2-methylcarbazole (15b), prepared by lipase-QLM catalyzed enantioselective transesterification of 3-hydroxy-1-(2-hydroxypropyl)-2-methylcarbazole (14), were used as the chiral starting material. | |||||
書誌情報 |
福山大学薬学部研究年報 en : Annual report of the Faculty of Pharmacy & Pharmaceutical Sciences, Fukuyama University 号 31, p. 23-23, 発行日 2013-12-25 |
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出版者 | ||||||
出版者 | 福山大学薬学部 | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0288-724X | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN10064550 |