{"created":"2023-06-19T09:51:25.499848+00:00","id":8593,"links":{},"metadata":{"_buckets":{"deposit":"ee6ba0ab-bbd4-4172-aa62-56b420a4e7d0"},"_deposit":{"created_by":18,"id":"8593","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"8593"},"status":"published"},"_oai":{"id":"oai:fukuyama-u.repo.nii.ac.jp:00008593","sets":["502:503:627:763"]},"author_link":["45110","45308","45310","45309"],"item_10002_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2010-12-25","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"28","bibliographicPageEnd":"41","bibliographicPageStart":"41","bibliographic_titles":[{"bibliographic_title":"福山大学薬学部研究年報"},{"bibliographic_title":"Annual report of the Faculty of Pharmacy & Pharmaceutical Sciences, Fukuyama University","bibliographic_titleLang":"en"}]}]},"item_10002_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The structure of inclusion complexes of gamma-cyclodextrin (gamma-CD), (-)-gallocatechin gallate (GCg), and (-)-epigallocatechin gallate (EGCg) in D(2)O was investigated using several NMR techniques. GCg formed a 1:1 inclusion complex with gamma-CD in which the A and C rings of GCg were inserted deep at the head of the A ring into the gamma-CD cavity from the wide secondary hydroxyl group side. In the 1:1 inclusion complex with GCg and gamma-CD, the GCg moiety maintained a conformation in which the B and B' rings of GCg took both pseudoequatorial positions with respect to the C ring. The structure of the inclusion complex of GCg and gamma-CD obtained from NMR experiments supported well that determined from PM6 semiempirical SCF MO calculations. However, (1)H NMR experiments suggested that EGCg did not form any inclusion complex with gamma-CD in D(2)O. The marked difference between GCg and EGCg in inclusion behavior toward gamma-CD may be explained in terms of the stabilization energy calculated with the PM6 method. .","subitem_description_type":"Abstract"}]},"item_10002_description_6":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"The structure of inclusion complexes of gamma-cyclodextrin (gamma-CD), (-)-gallocatechin gallate (GCg), and (-)-epigallocatechin gallate (EGCg) in D(2)O was investigated using several NMR techniques. GCg formed a 1:1 inclusion complex with gamma-CD in which the A and C rings of GCg were inserted deep at the head of the A ring into the gamma-CD cavity from the wide secondary hydroxyl group side. In the 1:1 inclusion complex with GCg and gamma-CD, the GCg moiety maintained a conformation in which the B and B' rings of GCg took both pseudoequatorial positions with respect to the C ring. The structure of the inclusion complex of GCg and gamma-CD obtained from NMR experiments supported well that determined from PM6 semiempirical SCF MO calculations. However, (1)H NMR experiments suggested that EGCg did not form any inclusion complex with gamma-CD in D(2)O. The marked difference between GCg and EGCg in inclusion behavior toward gamma-CD may be explained in terms of the stabilization energy calculated with the PM6 method. .","subitem_description_type":"Other"}]},"item_10002_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"福山大学薬学部"}]},"item_10002_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN10064550","subitem_source_identifier_type":"NCID"}]},"item_10002_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0288-724X","subitem_source_identifier_type":"ISSN"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"石津, 隆"}],"nameIdentifiers":[{"nameIdentifier":"45110","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"9000005188259","nameIdentifierScheme":"CiNii ID","nameIdentifierURI":"http://ci.nii.ac.jp/nrid/9000005188259"}]},{"creatorNames":[{"creatorName":"堤, 広之"}],"nameIdentifiers":[{"nameIdentifier":"45308","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"9000243751410","nameIdentifierScheme":"CiNii ID","nameIdentifierURI":"http://ci.nii.ac.jp/nrid/9000243751410"}]},{"creatorNames":[{"creatorName":"山本, 英二"}],"nameIdentifiers":[{"nameIdentifier":"45309","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"9000014625768","nameIdentifierScheme":"CiNii ID","nameIdentifierURI":"http://ci.nii.ac.jp/nrid/9000014625768"}]},{"creatorNames":[{"creatorName":"原野, 一誠"}],"nameIdentifiers":[{"nameIdentifier":"45310","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"9000005172077","nameIdentifierScheme":"CiNii ID","nameIdentifierURI":"http://ci.nii.ac.jp/nrid/9000005172077"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-01-27"}],"displaytype":"detail","filename":"水溶液中におけるシクロデキストリンとガレートカテキン類からなる包接錯体のNMR スペクトルの評価：空洞サイズの依存.pdf","filesize":[{"value":"511.3 kB"}],"format":"application/pdf","license_note":"Copyright (c) 2010 by Fukuyama University\n","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"水溶液中におけるシクロデキストリンとガレートカテキン類からなる包接錯体のNMR スペクトルの評価","url":"https://fukuyama-u.repo.nii.ac.jp/record/8593/files/水溶液中におけるシクロデキストリンとガレートカテキン類からなる包接錯体のNMR スペクトルの評価：空洞サイズの依存.pdf"},"version_id":"6ff5ee9d-91e3-404c-bf7d-13bf665b6df3"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Catechin","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Computer Simulation","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Deuterium Oxide","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Magnetic Resonance Spectroscopy","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Models, Chemical","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Models, Molecular","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Molecular Conformation","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Particle Size","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Quantum Theory","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Solutions","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Stereoisomerism","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Thermodynamics","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"gamma-Cyclodextrins","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"水溶液中におけるシクロデキストリンとガレートカテキン類からなる包接錯体のNMR スペクトルの評価：空洞サイズの依存(発表論文抄録(2009))","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"水溶液中におけるシクロデキストリンとガレートカテキン類からなる包接錯体のNMR スペクトルの評価：空洞サイズの依存(発表論文抄録(2009))"},{"subitem_title":"NMR spectroscopic characterization of inclusion complexes comprising cyclodextrins and gallated catechins in aqueous solution: cavity size dependency.","subitem_title_language":"en"}]},"item_type_id":"10002","owner":"18","path":["763"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-01-27"},"publish_date":"2017-01-27","publish_status":"0","recid":"8593","relation_version_is_last":true,"title":["水溶液中におけるシクロデキストリンとガレートカテキン類からなる包接錯体のNMR スペクトルの評価：空洞サイズの依存(発表論文抄録(2009))"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-06-19T10:20:54.497657+00:00"}