@article{oai:fukuyama-u.repo.nii.ac.jp:00007266, author = {桑田, 剛志 and 町支, 臣成 and 日比野, 俐}, journal = {福山大学薬学部研究年報, Annual report of the Faculty of Pharmacy & Pharmaceutical Sciences, Fukuyama University}, month = {}, note = {P(論文), Synthetic studies of bioactive products by two types of electrocyclic reactions of 6π electron systems have been described as follows; 1) the synthesis of mutagenic a-carbolines, AαC and MeAαC based on the thermal electrocyclic reaction of an 2-azahexatriene system involving an indole 2,3-bond, and 2) the asymmetric synthesis of β-carboline alkaloids, oxopropaline D and pyridindololes based on the thermal electrocyclic reaction of an 1-azahexatriene system involving an indole 2,3-bond, and the determination of an absolute configuration of (+)-oxopropaline D by the asymmetric synthesis of (R)-oxopropalin D acetonide based on the results of theoretical calculations by two ab initio MO methods. In addition, a new deprotection method of N-methoxymethyl-heterocyclic compounds and its utilization has been also described.}, pages = {1--24}, title = {生理活性ピリドインドール群の合成に関する研究}, volume = {22}, year = {2004} }