{"created":"2023-06-19T09:50:17.336405+00:00","id":7124,"links":{},"metadata":{"_buckets":{"deposit":"746eff09-d0bc-4474-b78a-9119f59b363c"},"_deposit":{"created_by":3,"id":"7124","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"7124"},"status":"published"},"_oai":{"id":"oai:fukuyama-u.repo.nii.ac.jp:00007124","sets":["502:503:627:644"]},"author_link":["37321","37316","37319","37318","37324","37323","37317","37326","37320","37325","37322","37327"],"item_1_biblio_info_14":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1999","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"76","bibliographicVolumeNumber":"17","bibliographic_titles":[{"bibliographic_title":"福山大学薬学部研究年報"},{"bibliographic_title":"Annual report of the Faculty of Pharmacy & Pharmaceutical Sciences, Fukuyama University","bibliographic_titleLang":"en"}]}]},"item_1_creator_6":{"attribute_name":"著者名(日)","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"井上, 裕文"}],"nameIdentifiers":[{"nameIdentifier":"37316","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"池野, 昌樹"}],"nameIdentifiers":[{"nameIdentifier":"37317","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"石井, ゆか"}],"nameIdentifiers":[{"nameIdentifier":"37318","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"鶴田, 泰人"}],"nameIdentifiers":[{"nameIdentifier":"37319","nameIdentifierScheme":"WEKO"}]}]},"item_1_description_1":{"attribute_name":"ページ属性","attribute_value_mlt":[{"subitem_description":"P(論文)","subitem_description_type":"Other"}]},"item_1_description_11":{"attribute_name":"抄録(日)","attribute_value_mlt":[{"subitem_description":"カルボン酸類の定量のためのプレカラムHPLC用蛍光誘導体化試薬として4-(5,6-ジメトキシ-2-フタルイミジニル)フェニルスルホニルセミピペラジドを開発した。本試薬は、縮合剤(トリフェニルポスフィン、2,2'-ジピリジルジスルフィド及びピリジンの混液)の存在下、カルボン酸類と100℃、15分で反応して強い蛍光を発する誘導体を生成し、誘導体はEx318nm及びEm380nmにおける蛍光検出を用いた逆相系HPLCにより分離検出された。検出限界(S/N=3)は4～12fmol/注入量であった。本試薬をイソクラティック溶出による人血清中の長鎖脂肪酸のHPLC分析に応用した。","subitem_description_type":"Other"}]},"item_1_description_12":{"attribute_name":"抄録(英)","attribute_value_mlt":[{"subitem_description":"A fluorescent labelling reagent, 4-(5,6-dimethoxy-2-phthalimidinyl)-phenylsulfonyl semipiperazide, was designed for the determination of carboxylic acids by precolumn HPLC. The reagent reacted with carboxylic acids at 100℃ for 15 min in the presence of an activating reagent (a mixture of triphenylphosphine, 2,2' -dipyridyl disulfide and pyridine) and produced highly fluorescent derivatives, which were separated on a reversed-phase column by fluorescence measurement at 317 nm (excitation) and 380 nm (emission). The detection limits were 4-12 fmol/injection. The reagent was used for HPLC assays of long chain fatty acids in human serum by isocratic elution.","subitem_description_type":"Other"}]},"item_1_full_name_7":{"attribute_name":"著者名よみ","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"37320","nameIdentifierScheme":"WEKO"}],"names":[{"name":"イノウエ, ヒロフミ"}]},{"nameIdentifiers":[{"nameIdentifier":"37321","nameIdentifierScheme":"WEKO"}],"names":[{"name":"イケノ, マサキ"}]},{"nameIdentifiers":[{"nameIdentifier":"37322","nameIdentifierScheme":"WEKO"}],"names":[{"name":"イシイ, ユカ"}]},{"nameIdentifiers":[{"nameIdentifier":"37323","nameIdentifierScheme":"WEKO"}],"names":[{"name":"ツルタ, ヤスト"}]}]},"item_1_full_name_8":{"attribute_name":"著者名(英)","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"37324","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Inoue, Hirofumi","nameLang":"en"}]},{"nameIdentifiers":[{"nameIdentifier":"37325","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Ikeno, Masaki","nameLang":"en"}]},{"nameIdentifiers":[{"nameIdentifier":"37326","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Ishii, Yuka","nameLang":"en"}]},{"nameIdentifiers":[{"nameIdentifier":"37327","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Tsuruta, Yasuto","nameLang":"en"}]}]},"item_1_source_id_13":{"attribute_name":"雑誌書誌ID","attribute_value_mlt":[{"subitem_source_identifier":"AN10064550","subitem_source_identifier_type":"NCID"}]},"item_1_text_10":{"attribute_name":"著者所属(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"FACULTY OF PHARMACY & PHARMACEUTICAL SCIENCES FUKUYAMA UNIVERSITY"},{"subitem_text_language":"en","subitem_text_value":"FACULTY OF PHARMACY & PHARMACEUTICAL SCIENCES FUKUYAMA UNIVERSITY"},{"subitem_text_language":"en","subitem_text_value":"FACULTY OF PHARMACY & PHARMACEUTICAL SCIENCES FUKUYAMA UNIVERSITY"},{"subitem_text_language":"en","subitem_text_value":"FACULTY OF PHARMACY & PHARMACEUTICAL SCIENCES FUKUYAMA UNIVERSITY"}]},"item_1_text_2":{"attribute_name":"記事種別(日)","attribute_value_mlt":[{"subitem_text_value":"発表論文抄録"}]},"item_1_text_9":{"attribute_name":"著者所属(日)","attribute_value_mlt":[{"subitem_text_value":"福山大学薬学部"},{"subitem_text_value":"福山大学薬学部"},{"subitem_text_value":"福山大学薬学部"},{"subitem_text_value":"福山大学薬学部"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"1999-01-01"}],"displaytype":"detail","filename":"KJ00005784723.pdf","filesize":[{"value":"49.9 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"url":"https://fukuyama-u.repo.nii.ac.jp/record/7124/files/KJ00005784723.pdf"},"version_id":"19e08e1b-d251-443a-9f89-17320e587af3"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"カルボン酸類のプレカラムHPLC分析用蛍光誘導体化試薬4-(5,6-ジメトキシ-2-フタルイミジニル)フェニルスルポニルセミピペラジド","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"カルボン酸類のプレカラムHPLC分析用蛍光誘導体化試薬4-(5,6-ジメトキシ-2-フタルイミジニル)フェニルスルポニルセミピペラジド"},{"subitem_title":"4-(5,6-Dimethoxy-2-phthalimidinyl) phenylsulfonyl Semipiperazide as a Fluorescent Labelling Reagent for Determination of Carboxylic Acids in Precolumn High Performance Liquid Chromatography","subitem_title_language":"en"}]},"item_type_id":"1","owner":"3","path":["644"],"pubdate":{"attribute_name":"公開日","attribute_value":"1999-01-01"},"publish_date":"1999-01-01","publish_status":"0","recid":"7124","relation_version_is_last":true,"title":["カルボン酸類のプレカラムHPLC分析用蛍光誘導体化試薬4-(5,6-ジメトキシ-2-フタルイミジニル)フェニルスルポニルセミピペラジド"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-06-19T10:49:32.420816+00:00"}