@article{oai:fukuyama-u.repo.nii.ac.jp:00007114, author = {石津, 隆 and 藤原, 正子 and 八木, 晟 and 野口, 俊作}, journal = {福山大学薬学部研究年報, Annual report of the Faculty of Pharmacy & Pharmaceutical Sciences, Fukuyama University}, month = {}, note = {P(論文), 朝鮮人参テトラペフ.チドH-L-Val-γ-D-Glu-D-Arg-Gly-OH(1)のDMSO-d_6溶液中におけるコソホメーションをNMRとコンピュータ(DADAS90)を用いた計算により決定した。このものは三つの分子内水素結合(D-ArgNH-L-ValCO,GlyNH-D-GluCO,GlyNH-GlyCO)により、剛直な骨格を有していることが判明した。, The ginseng tetrapeptide H-L-Val-γ-D-Glu-D-Arg-Gly-OH (1) was synthesized using a solution-phase methodology, and its solution conformation in dimethyl sulfoxide (DMS0)-d_6 was determined by a combination of NMR and computational techniques with the DADAS90 program. This compound has a rigid backbone based on three intramolecular hydrogen bonds between D-Arg NH and L-Val CO, between Gly NH and D-Glu CO, and between Gly NH and Gly CO.}, title = {朝鮮人参テトラペプチドH-L-Val-γ-D-Glu-D-Arg-Gly-OHの溶液中のコンホメーション}, volume = {17}, year = {1999} }